James B. Rawlings Research Group
Rahul Bindlish
Ph.D., University of Wisconsin-Madison, 2000
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Rahul Bindlish and James B. Rawlings.
Target linearization and model predictive control
of polymerization processes.
AIChE J., 49(11):2885-2899, November 2003.
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Rahul Bindlish, James B. Rawlings, and Robert E. Young.
Parameter estimation for industrial polymerization
processes.
AIChE J., 49(8):2071-2078, August 2003.
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Rahul Bindlish and James B. Rawlings.
Model predictive control of a prototypical copolymerization process.
Annual AIChE Meeting, Dallas, Texas, November 1999.
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Rahul Bindlish, James B. Rawlings, and Robert E. Young.
Parameter estimation in a dynamic model of a copolymerization
process.
In Proceedings of the 1997 American Control Conference, pages
2424-2428, 1997.
Modeling and Control of Polymerization Processes
This dissertation presents modeling and control of prototypical
industrial polymerization processes in the presence of disturbances
and plant-model mismatch. The process model consists of the material
and energy balances for the reactor, and simplified dynamic model for
the downstream separator. The kinetic expressions are simplified by
using the quasi-steady-state assumption for live polymer chains and
the moments of chain length distribution for the live and dead polymer
chains. The kinetic parameters in the process model are estimated from
industrial data sets using the maximum likelihood method to give a
validated fundamental model.
The process model is used to develop a model predictive controller
(MPC) for the copolymerization process with the following typical
characteristics
- Plant operations: plant start-up, product grade change,
regulation around a setpoint
- Regulated outputs: polymer production rate, copolymer
composition and viscosity
- Manipulated variables: vinyl acetate feed rate, acetaldehyde
feed rate, coolant temperature
- Measured disturbances: feed inhibitor, feed temperature
A target linearization model predictive controller gives superior
performance compared to a linear model predictive controller during
different plant operations.
The performance of the model predictive controllers is further
evaluated using the theoretical benchmark of a minimum variance
controller based on the process model. The modeling inadequacies that
impose limitations on the performance of the feedback controllers are
greater for the linear model in comparison to the non-linear model
based on the correlation analysis of the process data. Correlation
patterns also indicate that better feedback controller performance may
be obtained by incorporating a dynamic disturbance model for feed
inhibitor and feed temperature in the target linearization model
predictive controller.
University of Wisconsin
Department of Chemical Engineering
Madison WI 53706